1. 方法概述：
本檢驗方法適用于谷類、干豆類、干辣椒等食品中373項農(nóng)藥多重殘留分析 。
2. 檢驗方法：
樣品采用一步法快速萃取柱(FaPEx-cer)凈化后，以液相色譜串級質(zhì)譜儀(LC/MS/MS)及氣相色譜串級質(zhì)譜儀(GC/MS/MS)外標法分析。
3.設(shè)備：
3.1 液相色譜串級質(zhì)譜儀：
3.2 離子源：電噴霧電離源(ESI) 。
3.3色譜柱：CORTECS UPLC® ，C18，1.6 µm，內(nèi)徑2.1 mm × 10 cm，或 同級品 。
3.4保護柱：CORTECS UPLC® ,C18，1.6 µm，內(nèi)徑2.1 mm × 5 mm ， 或同級品 。
3.5氣相色譜串聯(lián)質(zhì)譜儀：
3.6離子源：電子轟擊源(EI) 。
3.7色譜柱：DB-5MS UI毛細管，內(nèi)膜厚度0.25 μm，內(nèi)徑0.25 mm×30 m ，或同級品。
3. 前處理操作步驟：
3.1.粉碎
谷類、干豆類、干辣椒類樣品以粉碎機磨粉，均質(zhì)后檢體取適量進行下述萃取及凈化步驟，若無法于當天進行分析，應(yīng)保存于 -20℃中 。
3.2. 干豆類、谷類及干辣椒類：
取均質(zhì)后稱重約0.5 g，置于離心管中，先加入去離子水1mL，混勻并靜置10分鐘再加入含1%醋酸之乙腈溶液5 mL，蓋上離心管蓋，隨即旋渦混勻30秒后，將萃取液注入一步法凈化柱FaPEx-cer，流速控制為1滴/秒，收集全部流出液，作為檢液原液。
取檢液原液1 mL ， 以濾膜過濾，上機以LC/MS/MS分析。
另取檢液原液1 mL，以氮氣吹至剛干，殘留物以丙酮：正己烷(1:1, v/v) 1mL溶解，混合均勻，經(jīng)濾膜過濾，上機以GC/MS/MS分析。
4.儀器分析條件
4.1 液相層析串聯(lián)質(zhì)譜分析測定條件：
移動相溶液：A液與B液以下列條件進行梯度分析
時間(min) | A (%) | B (%) |
0.0 → 2.0 | 99 → 50 | 1 → 50 |
2.0 → 8.0 | 50 → 30 | 50 → 70 |
8.0 → 10.0 | 30 → 1 | 70 → 99 |
10.0 → 13.0 | 1 → 1 | 99 → 99 |
13.0 → 13.5 | 1 → 99 | 99 → 1 |
13.5 → 15.0 | 99 → 99 | 1 → 1 |
移動相流速：0.3 mL/min 。
注入量：5 μL 。
毛細管電壓(Capillary voltage) ：
電灑離子化正離子(ESI＋)采用3.5 kV ，
電灑離子化負離子(ESI－)采用1.6 kV 。
離子源溫度(Ion source temperature)：150°C 。
溶媒揮散溫度(Desolvation temperature)：450°C 。
進樣錐氣體流速(Cone gas flow)：30 L/hr 。
溶媒揮散流速(Desolvation flow)：900 L/hr 。
偵測模式：多重反應(yīng)偵測(multiple reaction monitoring, MRM)。
4.2 GC/MS/MS ：氣相層析串聯(lián)質(zhì)譜分析測定條件：
層析管：DB-5MSUI毛細管，內(nèi)膜厚度0.25 μm，內(nèi)徑0.25 mm × 30 m。
層析管溫度：初溫：60°C， 1 min；
升溫速率：40°C/min；
中溫：170°C；
升溫速率：10°C/min；
終溫：310°C，2.25 min 。
移動相流速：氦氣，1 mL/min 。
注入器溫度(Injector temperature)：280°C 。
注入模式：不分流(splitless) 。
注入量：1 μL 。
離子化模式：電子撞擊游離(EI)，70 eV 。
離子源溫度：300°C 。
偵測模式：多重反應(yīng)偵測，偵測離子對及碰撞能量如表三。
注1：芬普尼之基質(zhì)匹配檢量線制作時，選擇適當之標準溶液添加 。
注2：上述測定條件分析不適時，可依所使用之儀器，設(shè)定適合的條件。
5、藥劑清單（回收率等結(jié)果，聯(lián)絡(luò)索?。?/span>
編號 | 英文名稱 | 中文名稱 | 分析方法 |
1 | Abamectin | 阿維菌素 | LC-MS/MS |
2 | Acephate | 乙酰甲胺lin磷 | LC-MS/MS |
3 | Acetamiprid | 啶蟲脒 | LC-MS/MS |
4 | Acibenzolar-S-methyl | 阿拉酸式苯-S-甲基 | LC-MS/MS |
5 | Aldicarb | 涕滅wei威 | LC-MS/MS |
6 | Aldicarbsulfone | 涕滅wei威砜 | LC-MS/MS |
7 | Aldicarbsulfoxide | 涕滅wei威亞砜 | LC-MS/MS |
8 | Alloxydim(sodium) | 禾草滅 | LC-MS/MS |
9 | Ametoctradin | 唑嘧菌胺 | LC-MS/MS |
10 | Ametryn | 莠滅凈 | LC-MS/MS |
11 | Amisulbrom | 吲唑磺菌胺 | LC-MS/MS |
12 | Atrazine | 莠去津 | LC-MS/MS |
13 | Azoxystrobin | 嘧菌酯 | LC-MS/MS |
14 | Benalaxyl | 苯霜靈 | LC-MS/MS |
15 | Bendiocarb | 惡蟲威 | LC-MS/MS |
16 | Benfuracarb | 丙硫克百wei威 | LC-MS/MS |
17 | Bensulfuron-methyl | 芐嘧磺隆 | LC-MS/MS |
18 | Benthiazole | 苯噻硫氰 | LC-MS/MS |
19 | Bifenazate | 聯(lián)苯肼酯 | LC-MS/MS |
20 | Boscalid | 啶酰菌胺 | LC-MS/MS |
21 | Bufencarb | 合殺威 | LC-MS/MS |
22 | Buprofezin | 噻嗪酮 | LC-MS/MS |
23 | Butocarboxim | 丁酮威 | LC-MS/MS |
24 | Carbaryl | 甲萘威 | LC-MS/MS |
25 | Carbendazim | 多菌靈 | LC-MS/MS |
26 | Carbofuran | 克百wei威 | LC-MS/MS |
27 | 3-ketoCarbofuran | 3-酮基呋nan喃丹 | LC-MS/MS |
28 | 3-OHCarbofuran | 3-羥基呋nan喃丹 | LC-MS/MS |
29 | Carbosulfan | 丁硫克bai百威 | LC-MS/MS |
30 | Carfentrazone-ethyl | 唑草酮 | LC-MS/MS |
31 | Carpropamid | 加普胺 | LC-MS/MS |
32 | Chlorantraniliprole | 氯蟲苯甲酰胺 | LC-MS/MS |
33 | Chlorfluazuron | 氟啶脲 | LC-MS/MS |
34 | Chromafenozide | 環(huán)蟲酰肼 | LC-MS/MS |
35 | Cinern I | 除蟲菊精 I | LC-MS/MS |
36 | Cinern II | 除蟲菊精 II | LC-MS/MS |
37 | Cinosulfuron | 醚磺隆 | LC-MS/MS |
38 | Clethodim | 烯草酮 | LC-MS/MS |
39 | Clofentezine | 四螨嗪 | LC-MS/MS |
40 | Clomazone | 異惡草酮 | LC-MS/MS |
41 | Clomeprop | 氯甲酰草胺 | LC-MS/MS |
42 | Clothianidin | 噻蟲胺 | LC-MS/MS |
43 | Cyanazine | 氰草津 | LC-MS/MS |
44 | Cyazofamid | 氰霜唑 | LC-MS/MS |
45 | Cyclosulfamuron | 環(huán)丙嘧磺隆 | LC-MS/MS |
46 | Cycloxydim | 噻草酮 | LC-MS/MS |
47 | Cyflufenamid | 環(huán)氟菌胺 | LC-MS/MS |
48 | Cyflumetofen | 丁氟螨酯 | LC-MS/MS |
49 | Cymoxanil | 霜脲氰 | LC-MS/MS |
50 | Cyprodinil | 嘧菌環(huán)胺 | LC-MS/MS |
51 | Demeton-S-methyl | 甲基內(nèi)xi吸磷 | LC-MS/MS |
52 | Dicrotophos | 百治lin磷 | LC-MS/MS |
53 | Dimethenamid | 二甲吩草胺 | LC-MS/MS |
54 | Dimethoate | 樂果 | LC-MS/MS |
55 | Dimethomorph | 烯酰嗎啉 | LC-MS/MS |
56 | Dinotefuran | 呋蟲胺 | LC-MS/MS |
57 | Diuron | 敵草隆 | LC-MS/MS |
58 | Dymron | 殺草隆 | LC-MS/MS |
59 | EmamectinbenzoateB1a | 甲氨基阿維菌素B1a苯甲酸鹽 | LC-MS/MS |
60 | EmamectinbenzoateB1b | 甲氨基阿維菌素B1b苯甲酸鹽 | LC-MS/MS |
61 | Ethiprole | 乙蟲腈 | LC-MS/MS |
62 | Ethirimol | 乙嘧酚 | LC-MS/MS |
63 | Etoxazole | 乙螨唑 | LC-MS/MS |
64 | Famoxadone | 噁唑菌酮 | LC-MS/MS |
65 | Fenamiphos | 苯線lin磷 | LC-MS/MS |
66 | Fenazaquin | 喹螨醚 | LC-MS/MS |
67 | Fenbutatin-oxide | 苯丁錫 | LC-MS/MS |
68 | Fenhexamid | 環(huán)酰菌胺 | LC-MS/MS |
69 | Fenobucarb | 仲丁威 | LC-MS/MS |
70 | Fenothiocarb | 苯硫威 | LC-MS/MS |
71 | Fenoxanil | 稻瘟酰胺 | LC-MS/MS |
72 | Fenoxycarb | 苯氧威 | LC-MS/MS |
73 | Fenpyroximate | 唑螨酯 | LC-MS/MS |
74 | Fenthion | 倍硫lin磷 | LC-MS/MS |
75 | Ferimzone | 嘧菌腙 | LC-MS/MS |
76 | Flazasulfuron | 啶嘧黃隆 | LC-MS/MS |
77 | Flonicamid | 氟啶蟲酰胺 | LC-MS/MS |
78 | Fluazifop-P-butyl | 吡氟禾草靈 | LC-MS/MS |
79 | Fludioxonil | 咯菌腈 | LC-MS/MS |
80 | Flufenoxuron | 氟蟲脲 | LC-MS/MS |
81 | Fluopicolide | 氟吡菌胺 | LC-MS/MS |
82 | Fluopyram | 氟吡菌酰胺 | LC-MS/MS |
83 | Flupyradifurone | 氟吡呋喃酮 | LC-MS/MS |
84 | Flusilazole | 氟硅唑 | LC-MS/MS |
85 | Flutriafol | 粉唑醇 | LC-MS/MS |
86 | Formetanate | 伐蟲脒 | LC-MS/MS |
87 | Fosthiazate | 噻唑磷 | LC-MS/MS |
88 | Furametpyr | 呋吡菌胺 | LC-MS/MS |
89 | Haloxyfop-methyl | 氟吡甲禾靈 | LC-MS/MS |
90 | Hexaconazole | 己唑醇 | LC-MS/MS |
91 | Hexaflumuron | 氟鈴脲 | LC-MS/MS |
92 | Hexythiazox | 噻螨酮 | LC-MS/MS |
93 | Imazalil | 抑霉唑 | LC-MS/MS |
94 | Imidacloprid | 吡蟲啉 | LC-MS/MS |
95 | Indoxacarb | 茚蟲威 | LC-MS/MS |
96 | Iprovalicarb | 纈霉威 | LC-MS/MS |
97 | Isazofos | 氯唑lin磷 | LC-MS/MS |
98 | Isoprocarb | 異丙威 | LC-MS/MS |
99 | Isopyrazam | 吡唑萘菌胺 | LC-MS/MS |
100 | Isouron | 異惡隆 | LC-MS/MS |
101 | Isoxaflutole | 異惡唑草酮 | LC-MS/MS |
102 | JasmolinI | 茉酮菊素I | LC-MS/MS |
103 | JasmolinII | 茉酮菊素II | LC-MS/MS |
104 | Linuron | 利谷隆 | LC-MS/MS |
105 | Mandipropamid | 雙炔酰菌胺 | LC-MS/MS |
106 | Mecarbam | 滅蚜磷 | LC-MS/MS |
107 | Mepanipyrim | 嘧菌胺 | LC-MS/MS |
108 | Metaflumizone | 氰氟蟲腙 | LC-MS/MS |
109 | Metalaxyl | 甲霜靈 | LC-MS/MS |
110 | Metconazole-cis | 順式-葉菌唑 | LC-MS/MS |
111 | Methamidophos | 甲胺lin磷 | LC-MS/MS |
112 | Methiocarb | 甲硫威 | LC-MS/MS |
113 | Methomyl | 滅多威 | LC-MS/MS |
114 | Methoprene | 烯蟲酯 | LC-MS/MS |
115 | Methoxyfenozide | 甲氧蟲酰肼 | LC-MS/MS |
116 | Metobromuron | 溴谷隆 | LC-MS/MS |
117 | Metolcarb | 速滅wei威 | LC-MS/MS |
118 | Metrafenone | 苯菌酮 | LC-MS/MS |
119 | Metribuzin | 嗪草酮 | LC-MS/MS |
120 | Mevinphos | 速滅磷 | LC-MS/MS |
121 | Monocrotophos | 久效lin磷 | LC-MS/MS |
122 | MPMC(Xylylcarb) | 滅殺威 | LC-MS/MS |
123 | Norflurazon | 噠草伏 | LC-MS/MS |
124 | Novaluron | 氟酰脲 | LC-MS/MS |
125 | Omethoate | 氧樂果 | LC-MS/MS |
126 | Oxamyl | 殺線威 | LC-MS/MS |
127 | Oxycarboxin | 氧化萎銹靈 | LC-MS/MS |
128 | Oxydemeton-Methyl | 亞砜磷 | LC-MS/MS |
129 | Pencycuron | 戊菌隆 | LC-MS/MS |
130 | Penoxsulam | 五氟磺草胺 | LC-MS/MS |
131 | Phosphamidon | 磷an胺 | LC-MS/MS |
132 | Phoxim | 辛硫lin磷 | LC-MS/MS |
133 | Piperonylbutoxide | 增效醚 | LC-MS/MS |
134 | Pirimicarb | 抗蚜wei威 | LC-MS/MS |
135 | Pretilachlor | 丙草胺 | LC-MS/MS |
136 | Probenazole | 烯丙苯噻唑 | LC-MS/MS |
137 | Prochloraz | 咪酰胺 | LC-MS/MS |
138 | Profenophos | 丙溴磷 | LC-MS/MS |
139 | Promecarb | 猛殺威 | LC-MS/MS |
140 | Propamocarb hydrochloride | 霜霉威鹽酸鹽 | LC-MS/MS |
141 | Propanil | 敵稗 | LC-MS/MS |
142 | Propargite | 炔螨特 | LC-MS/MS |
143 | Propoxur | 殘殺威 | LC-MS/MS |
144 | Proquinazid | 丙氧喹啉 | LC-MS/MS |
145 | Pymetrozine | 吡蚜酮 | LC-MS/MS |
146 | Pyraclostrobin | 吡唑醚菌酯 | LC-MS/MS |
147 | Pyrazosulfuron-ethyl | 吡嘧磺隆 | LC-MS/MS |
148 | PyrethrinI | 除蟲菊素I | LC-MS/MS |
149 | PyrethrinII | 除蟲菊素II | LC-MS/MS |
150 | Pyribencarb | 吡菌苯威 | LC-MS/MS |
151 | Pyridaben | 噠螨靈 | LC-MS/MS |
152 | Pyrifluquinazon | 吡啶喹唑啉 | LC-MS/MS |
153 | Pyridate | 噠草特 | LC-MS/MS |
154 | Pyrifenox | 碇斑肟 | LC-MS/MS |
155 | Quinoxyfen | 喹氧靈 | LC-MS/MS |
156 | Quizalofop-ethyl | 喹禾靈 | LC-MS/MS |
157 | Rotenone | 魚藤酮 | LC-MS/MS |
158 | Saflufenacil | 苯嘧磺草胺 | LC-MS/MS |
159 | Sethoxydim | 烯禾啶 | LC-MS/MS |
160 | Simazine | 西瑪津 | LC-MS/MS |
161 | SpinetoramJ | 乙基多殺菌素 J | LC-MS/MS |
162 | SpinetoramL | 乙基多殺菌素 L | LC-MS/MS |
163 | SpinosadA | 多殺霉素A | LC-MS/MS |
164 | SpinosadD | 多殺霉素D | LC-MS/MS |
165 | Spirodiclofen | 螺螨酯 | LC-MS/MS |
166 | Spiromesifen | 螺甲螨酯 | LC-MS/MS |
167 | Spirotetramat | 螺蟲乙酯 | LC-MS/MS |
168 | Sulfoxaflor | 氟啶蟲胺腈 | LC-MS/MS |
169 | Tebufenozide | 蟲酰肼 | LC-MS/MS |
170 | Tebufenpyrad | 吡螨胺 | LC-MS/MS |
171 | Tepraloxydim | 得殺草 | LC-MS/MS |
172 | Thiabendazole | 噻菌靈 | LC-MS/MS |
173 | Thiacloprid | 噻蟲啉 | LC-MS/MS |
174 | Thiamethoxam | 噻蟲嗪 | LC-MS/MS |
175 | Thiobencarb | 禾草丹 | LC-MS/MS |
176 | Thiodicarb | 硫雙威 | LC-MS/MS |
177 | Thiofanox | 久效wei威砜 | LC-MS/MS |
178 | Tolfenpyrad | 唑蟲酰胺 | LC-MS/MS |
179 | Tolyfluanid | 對甲抑菌靈 | LC-MS/MS |
180 | Trichlorfon | 敵百chong蟲 | LC-MS/MS |
181 | Tricyclazole | 三環(huán)唑 | LC-MS/MS |
182 | Trifloxystrobin | 肟菌酯 | LC-MS/MS |
183 | Triforine | 嗪氨靈 | LC-MS/MS |
184 | Vamidothion | 蚜滅磷 | LC-MS/MS |
185 | XMC(Macbal) | 二甲威 | LC-MS/MS |
186 | Zoxamide | 苯酰菌胺 | LC-MS/MS |
187 | Acequinocyl- | 羥基滅螨醌 | LC-MS/MS |
188 | Bentazone | 滅草松 | LC-MS/MS |
189 | Diflubenzuron | 除蟲脲 | LC-MS/MS |
190 | Fipronil | 氟蟲腈 | LC-MS/MS |
191 | Fipronil-sulfone | 氟蟲腈砜 | LC-MS/MS |
192 | Fluazinam | 氟啶胺 | LC-MS/MS |
193 | Flubendiamide | 氟苯蟲酰胺 | LC-MS/MS |
194 | Lufenuron | 虱螨脲 | LC-MS/MS |
195 | Penthiopyrad | 吡噻菌胺 | LC-MS/MS |
196 | Teflubenzuron | 氟苯脲 | LC-MS/MS |
197 | Acetochlor | 乙草胺 | GC-MSMS |
198 | Acrinathrin | 氟酯菊酯 | GC-MSMS |
199 | Alachlor | 甲草胺 | GC-MSMS |
200 | Aldrin | 艾氏ji劑 | GC-MSMS |
201 | Allethrin | 丙烯菊酯 | GC-MSMS |
202 | Azinphos-methyl | 保棉磷 | GC-MSMS |
203 | Benfluralin | 苯氟拉林 | GC-MSMS |
204 | α-BHC | α-六六六 | GC-MSMS |
205 | β-BHC | β-六六六 | GC-MSMS |
206 | γ-BHC(Lindane) | γ-六六六 | GC-MSMS |
207 | δ-BHC | δ-六六六 | GC-MSMS |
208 | Bifenox | 甲羧除草醚 | GC-MSMS |
209 | Bifenthrin | 聯(lián)苯菊酯 | GC-MSMS |
210 | Bitertanol | 聯(lián)苯三唑醇 | GC-MSMS |
211 | Bromacil | 除草定 | GC-MSMS |
212 | Bromophos-ethyl | 乙基溴硫磷 | GC-MSMS |
213 | Bromophos-methyl | 甲基溴硫磷 | GC-MSMS |
214 | Bromopropylate | 溴螨酯 | GC-MSMS |
215 | Bromuconazole | 糠菌唑 | GC-MSMS |
216 | Bupirimate | 乙嘧酚磺酸酯 | GC-MSMS |
217 | Butachlor | 丁草胺 | GC-MSMS |
218 | Butralin | 仲丁靈 | GC-MSMS |
219 | Cadusafos | 硫線磷 | GC-MSMS |
220 | Carbophenothion | 三硫lin磷 | GC-MSMS |
221 | Chinomethionat | 滅螨猛 | GC-MSMS |
222 | cis-Chlordane | 順-氯丹 | GC-MSMS |
223 | trans-Chlordane | 反-氯丹 | GC-MSMS |
224 | Chlorfenapyr | 蟲螨腈 | GC-MSMS |
225 | Chloropropylate | 氯丙基 | GC-MSMS |
226 | Chlorothalonil | 百菌清 | GC-MSMS |
227 | Chlorpropham | 氯苯胺靈 | GC-MSMS |
228 | Chlorpyrifos | 毒死蜱 | GC-MSMS |
229 | Chlorpyrifos-methyl | 甲基毒死蜱 | GC-MSMS |
230 | Chlorthal-dimethyl | 氯酞酸二甲酯 | GC-MSMS |
231 | Chlozolinate | 克氯得 | GC-MSMS |
232 | CPMC(Etrofol) | 害樸威 | GC-MSMS |
233 | Cyanofenphos | 氰硫磷 | GC-MSMS |
234 | Cyanophos | 殺螟腈 | GC-MSMS |
235 | Cyfluthrin | 氟氯氰菊酯 | GC-MSMS |
236 | Cyhalofop-butyl | 氰氟草脂 | GC-MSMS |
237 | λ-Cyhalothrin | 高效氯氟氰菊酯 | GC-MSMS |
238 | Cypermethrin | 氯氰菊酯 | GC-MSMS |
239 | α-cypermethrin | α-氯氰菊酯 | GC-MSMS |
240 | Cyproconazole | 環(huán)丙唑醇 | GC-MSMS |
241 | o,p’-DDD | o,p’-DDD | GC-MSMS |
242 | o,p’-DDE | o,p’-DDE | GC-MSMS |
243 | o,p'-DDT | o,p'-DDT | GC-MSMS |
244 | p,p’-DDE | p,p’-DDE | GC-MSMS |
245 | p,p’-DDT | p,p’-DDT | GC-MSMS |
246 | p,p'-DDD | p,p'-DDD | GC-MSMS |
247 | Deltamethrin | 溴氰菊酯 | GC-MSMS |
248 | Diazinon | 二嗪磷 | GC-MSMS |
249 | Dichlorvos | 敵敵wei畏 | GC-MSMS |
250 | Dicloran | 氯硝胺 | GC-MSMS |
251 | Dicofol | 三氯殺man螨醇 | GC-MSMS |
252 | Dicofol(DCBP) | o,p'-三氯殺man螨醇 | GC-MSMS |
253 | Dieldrin | 狄氏ji劑 | GC-MSMS |
254 | Difenoconazole | 苯醚甲環(huán)唑 | GC-MSMS |
255 | 2,6-Diisopropylnaphthalene | 2,6-二異丙基萘 | GC-MSMS |
256 | Dimethipin | 噻節(jié)因 | GC-MSMS |
257 | Diniconazole | 烯唑醇 | GC-MSMS |
258 | Dinitramine | 敵樂胺 | GC-MSMS |
259 | Diphenamid | 二苯胺 | GC-MSMS |
260 | Diphenylamine | 二苯胺 | GC-MSMS |
261 | Disulfoton | 乙拌lin磷 | GC-MSMS |
262 | Ditalimfos | 滅菌磷 | GC-MSMS |
263 | Dithiopyr | 氟硫草定 | GC-MSMS |
264 | Edifenphos | 敵瘟磷 | GC-MSMS |
265 | “-Endosulfan | 硫丹 | GC-MSMS |
266 | β-Endosulfan | β-硫丹 | GC-MSMS |
267 | Endosulfan-sulfate | 硫丹硫酸酯 | GC-MSMS |
268 | Endrin | 異狄氏ji劑 | GC-MSMS |
269 | EPN | 苯硫磷 | GC-MSMS |
270 | Epoxiconazole | 氟環(huán)唑 | GC-MSMS |
271 | Esfenvalerate | S-氰戊ju菊酯 | GC-MSMS |
272 | Ethion | 乙硫lin磷 | GC-MSMS |
273 | Ethoprophos | 滅線lin磷 | GC-MSMS |
274 | Etofenprox | 醚菊酯 | GC-MSMS |
275 | Etridiazole | 氯唑靈 | GC-MSMS |
276 | Etrimfos | 乙嘧硫磷 | GC-MSMS |
277 | Fenarimol | 氯苯嘧啶醇 | GC-MSMS |
278 | Fenbuconazole | 腈苯唑 | GC-MSMS |
279 | Fenitrothion | 殺螟硫磷 | GC-MSMS |
280 | Fenoxaprop-ethyl | 精噁唑禾草靈 | GC-MSMS |
281 | Fenpropathrin | 甲氰菊ju酯 | GC-MSMS |
282 | Fenpropimorph | 丁苯嗎啉 | GC-MSMS |
283 | Fensulfothion | 苯磺硫磷 | GC-MSMS |
284 | Fenvalerate | 氰戊菊ju酯 | GC-MSMS |
285 | Flucythrinate | 氟氰戊菊ju酯 | GC-MSMS |
286 | Fluensulfone | 氟砜靈 | GC-MSMS |
287 | Fluroxypyr-meptyl | 氟草煙 | GC-MSMS |
288 | Flutolanil | 氟酰胺 | GC-MSMS |
289 | Fluvalinate | 氟胺氰菊酯 | GC-MSMS |
290 | Fluxapyroxad | 氟唑菌酰胺 | GC-MSMS |
291 | Fonofos | 地蟲磷 | GC-MSMS |
292 | Formothion | 安硫磷 | GC-MSMS |
293 | Fthalide | 四氯苯酞 | GC-MSMS |
294 | Halfenprox | 芐螨醚 | GC-MSMS |
295 | Heptachlor | 七氯 | GC-MSMS |
296 | Heptachlorepoxide | 環(huán)氧七氯 | GC-MSMS |
297 | Heptenophos | 庚烯磷 | GC-MSMS |
298 | Hexazinone | 環(huán)嗪酮 | GC-MSMS |
299 | Imibenconazole | 亞胺唑 | GC-MSMS |
300 | Iprobenfos | 異稻瘟wen凈 | GC-MSMS |
301 | Iprodione | 異菌脲 | GC-MSMS |
302 | Isofenphos | 異丙胺磷 | GC-MSMS |
303 | Isoprothiolane | 稻瘟靈 | GC-MSMS |
304 | Isotianil | 異噻菌胺 | GC-MSMS |
305 | Isoxathion | 異惡硫磷 | GC-MSMS |
306 | Kresoxim-methyl | 醚菌酯 | GC-MSMS |
307 | Malathion | 馬拉硫liu磷 | GC-MSMS |
308 | Mefenacet | 苯噻酰草胺 | GC-MSMS |
309 | Mephosfolan | 甲氧麻黃huang酮 | GC-MSMS |
310 | Mepronil | 滅銹胺 | GC-MSMS |
311 | Metazachlor | 吡唑草胺 | GC-MSMS |
312 | Methacrifos | 蟲螨畏 | GC-MSMS |
313 | Methidathion | 殺撲磷 | GC-MSMS |
314 | Methylpentachlorophenyl | 五氯硫代苯甲醚 | GC-MSMS |
315 | Metolachlor | 異丙甲草胺 | GC-MSMS |
316 | Mirex | 滅蟻靈 | GC-MSMS |
317 | Molinate | 草達滅 | GC-MSMS |
318 | Myclobutanil | 腈菌唑 | GC-MSMS |
319 | Napropamide | 敵草胺 | GC-MSMS |
320 | Nuarimol | 氟苯嘧啶醇 | GC-MSMS |
321 | Oxadiazon | 噁草酮 | GC-MSMS |
322 | Oxadixyl | 噁霜靈 | GC-MSMS |
323 | Oxyfluorfen | 乙氧氟草醚 | GC-MSMS |
324 | Paclobutrazol | 多效唑 | GC-MSMS |
325 | Parathion | 對硫lin磷 | GC-MSMS |
326 | Parathion-methyl | 甲基對硫lin磷 | GC-MSMS |
327 | Penconazole | 戊菌唑 | GC-MSMS |
328 | Pendimethalin | 二甲戊靈 | GC-MSMS |
329 | Penflufen | 氟唑菌苯胺 | GC-MSMS |
330 | Pentachloroaniline | 五氯苯胺 | GC-MSMS |
331 | Permethrin | 氯菊酯 | GC-MSMS |
332 | Phenothiol | 酚硫殺 | GC-MSMS |
333 | Phenothrin | 苯醚菊酯 | GC-MSMS |
334 | Phenthoate | 稻豐san散 | GC-MSMS |
335 | 2-Phenylphenol | 2-苯基苯酚 | GC-MSMS |
336 | Phorate | 甲拌lin磷 | GC-MSMS |
337 | Phosalone | 伏殺硫磷 | GC-MSMS |
338 | Phosmet | 亞胺硫lin磷 | GC-MSMS |
339 | Pirimiphos-ethyl | 乙基蟲螨磷 | GC-MSMS |
340 | Pirimiphos-methyl | 甲基嘧啶磷 | GC-MSMS |
341 | Procymidone | 腐霉利 | GC-MSMS |
342 | Prometryn | 撲草凈 | GC-MSMS |
343 | Propaphos | 丙蟲磷 | GC-MSMS |
344 | Propiconazole | 丙環(huán)唑 | GC-MSMS |
345 | Prothiofos | 丙硫磷 | GC-MSMS |
346 | Pyraclofos | 吡唑硫磷 | GC-MSMS |
347 | Pyraflufen-ethyl | 吡草醚 | GC-MSMS |
348 | Pyrazophos | 吡菌磷 | GC-MSMS |
349 | Pyridaphenthion | 噠嗪硫磷 | GC-MSMS |
350 | Pyrimethanil | 嘧霉胺 | GC-MSMS |
351 | Pyrimidifen | 嘧螨醚 | GC-MSMS |
352 | Pyriproxyfen | 吡丙醚 | GC-MSMS |
353 | Pyroquilon | 咯喹酮 | GC-MSMS |
354 | Quinalphos | 喹硫磷 | GC-MSMS |
355 | Quintozene(PCNB) | 五氯硝基苯 | GC-MSMS |
356 | Salithion | 水楊硫磷 | GC-MSMS |
357 | Sedaxane | 氟唑環(huán)菌胺 | GC-MSMS |
358 | Silafluofen | 氟硅菊酯 | GC-MSMS |
359 | Tebuconazole | 戊唑醇 | GC-MSMS |
360 | Terbufos | 特丁硫lin磷 | GC-MSMS |
361 | Tetraconazole | 四氟醚唑 | GC-MSMS |
362 | Tetradifon | 三氯殺螨砜 | GC-MSMS |
363 | Tetramethrin | 胺菊酯 | GC-MSMS |
364 | Thenylchlor | 甲氧噻草胺 | GC-MSMS |
365 | Thifluzamide | 噻呋酰胺 | GC-MSMS |
366 | Thiometon | 甲基乙拌lin磷 | GC-MSMS |
367 | Tolclofos-methyl | 甲基立枯磷 | GC-MSMS |
368 | Triadimefon | 三唑酮 | GC-MSMS |
369 | Triadimenol | 三唑醇 | GC-MSMS |
370 | Triazophos | 三唑磷 | GC-MSMS |
371 | Tridiphane | 滅草環(huán) | GC-MSMS |
372 | Triflumizole | 氟菌唑 | GC-MSMS |
373 | Trifluralin | 氟樂靈 | GC-MSMS |
374 | Vinclozolin | 乙烯菌核利 | GC-MSMS |
5
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